Smith, Wiser, Anderson, and Krajcik (2006): The Source of the Properties-First Sequence
"Research as yet provides few longitudinal studies documenting this process developmentally, but studies of conceptions of matter, material kind, and related physical and chemical entities in students of different ages, as well as the results of intervention studies, enable us to piece together a possible learning progression culminating in the mastery of the basic tenets of the atomic-molecular theory. We call it a possible rather than actual learning progression for three reasons. First, we do not have evidence that this is the progression most students actually take; our learning progression represents a conjecture about a coherent possible path based on existing literature. Second, we do not assume that this is the only sensible or coherent path that might be taken or constructed, but it is at least one sensible one. If multiple alternatives were outlined by others, then one could research the trade-offs in different approaches. Finally, at present, many students do not actually make it through the progression, although research suggests with good instruction many more could actually do so."
Smith et al., 2006, p. 26
Smith, C. L., Wiser, M., Anderson, C. W., and Krajcik, J. (2006). Implications of research on children's learning for standards and assessment: A proposed learning progression for matter and the atomic-molecular theory. Assessment of Teaching and Learning, pp. 41-98. National Research Council.
The NGSS properties-first sequence is based on this paper. Its own authors called it a conjecture, acknowledged it lacks longitudinal evidence, and explicitly invited alternative progressions to be researched and compared. RS4K is that alternative.
Haeusler and Donovan (2020)
Elementary Students Can Learn Atomic-Molecular Theory with Appropriate Instruction
Published in Research in Science Education, this study directly challenged the properties-first paradigm by demonstrating that primary-age children successfully learn atomic-molecular theory when instruction is appropriately scaffolded. The authors concluded that the conventional "properties first" sequence is not a developmental necessity but a pedagogical choice, and that starting with atomic structure is a viable and effective alternative.
Haeusler, C., and Donovan, J. (2020). Challenging the science curriculum paradigm: Teaching primary children atomic-molecular theory. Research in Science Education, 50, 2243-2264.
Samarapungavan, Bryan, and Wills (2017)
2nd Graders Develop Particle Models of Matter through Inquiry-Based Instruction
This study, also in Research in Science Education, documented that second-grade students develop sophisticated emerging particle models of matter when given structured inquiry-based instruction. Students as young as six demonstrated the ability to reason about matter at the particle level and to use those models to explain observable phenomena. The study supports teaching atomic concepts well before middle school.
Samarapungavan, A., Bryan, L. A., and Wills, J. (2017). Second graders' emerging particle models of matter in the context of inquiry-based instruction. Research in Science Education, 47(2), 303-327.
Samarapungavan, Willis, and Bryan (2021)
Technology-Mediated Inquiry Develops Elementary Students' Conceptual Understanding of Matter
A follow-up study in the Journal of Research in Science Teaching showed that discourse-scaffolded, technology-mediated inquiry helps elementary students build durable conceptual understanding of matter at the atomic level. Students who developed particle-level models showed stronger explanatory capability and more coherent understanding of physical and chemical properties than those taught through conventional macroscopic approaches.
Samarapungavan, A., Willis, J., and Bryan, L. A. (2021). Developing elementary students' conceptual understanding of matter through discourse-scaffolded, technology-mediated inquiry. Journal of Research in Science Teaching, 58(1), 3-33.
Park, Light, Swarat, and Drane (LeaPS 2009)
An Atoms-First Learning Progression for Atomic Structure Starting in Early Grades
Presented at the Learning Progressions in Science (LeaPS) conference, this paper proposed an atoms-first learning progression for atomic structure that begins with atoms at the elementary level, similar to the progression used in the RS4K Science textbooks. The authors used variation theory to document how students conceptualize atomic structure progressively across grade levels, providing a theoretical and empirical basis for starting with atomic concepts rather than macroscopic properties.
Park, E. J., Light, G., Swarat, S., and Drane, D. (2009). Understanding learning progression in student conceptualization of atomic structure by variation theory for learning. LeaPS Conference, Iowa City, IA.